• Vi Rapp

New Publication: Breaking records with new thermoelectric generator design

Congratulations to the team for our recent publication in Nature Communications. Our technology uses wafer-scale arrays of porous silicon nanowires with ultra-thin silicon crystallite that allows for an 18 times greater “figure of merit” (an expression representing performance or efficiency) than other high-temperature or bulk silicon thermoelectric technologies. A brief summary of the article and the link to the full article are below. A news release from Berkeley Lab can also be found here.

Thermoelectrics operating at high temperature can cost-effectively convert waste heat and compete with other zero-carbon technologies. Among different high-temperature thermoelectrics materials, silicon nanowires possess the combined attributes of cost effectiveness and mature manufacturing infrastructures. Despite significant breakthroughs in silicon nanowires based thermoelectrics for waste heat conversion, the figure of merit (ZT) or operating temperature has remained low. Here, we report the synthesis of large-area, wafer-scale arrays of porous silicon nanowires with ultra-thin Si crystallite size of ~4 nm. Concurrent measurements of thermal conductivity (κ), electrical conductivity (σ), and Seebeck coefficient (S) on the same nanowire show a ZT of 0.71 at 700 K, which is more than ~18 times higher than bulk Si. This ZT value is more than two times higher than any nanostructured Si-based thermoelectrics reported in the literature at 700 K. Experimental data and theoretical modeling demonstrate that this work has the potential to achieve a ZT of ~1 at 1000 K.

Click here for the full article.

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