A systematic method for selecting molecular descriptors as features when training models for predicting physiochemical properties
We present a method for systematically selecting molecular descriptor features and developing interpretable machine learning models without sacrificing accuracy. Our method simplifies the process of selecting features by reducing feature multicollinearity and enables discoveries of new relationships between global properties and molecular descriptors. To demonstrate our approach, we developed models for predicting melting point, boiling point, flash point, yield sooting index, and net heat of combustion with the help of the Tree-based Pipeline Optimization Tool (TPOT).
The Co-Optimization of Sustainable Aviation Fuel: Cost, Emissions, and Performance
This research explores 3 potential sorghum derived jet fuel molecules from 4 different production routes, hydro-processed esters and fatty acids (HEFA), and Jet A, to identify how blends including these fuels could offer improved performance (MJ/kg, MJ/L) and improved emissions (gCO2/MJ) while minimizing costs.
Safety and Effectiveness of a Non-Electric Infant Warmer for Hypothermia in Rwanda: A Cluster-Randomized Stepped-Wedge Trial
We conducted a cluster-randomized stepped-wedge trial. The primary aim was to assess the effect on overall euthermia rates of introducing the warmer compared to standard of care in rural Rwandan hospitals. The secondary aims were to assess effects of warmer introduction on mortality, as well as the safety and feasibility of the warmer.
Practical design considerations for secondary air injection in wood-burning cookstoves: An experimental study
We use a modular cookstove platform to experimentally quantify the practical secondary air injection design requirements to reduce harmful emissions by at least 90% relative to a traditional cooking fire.
Optimization of Secondary Air Injection in a Wood-Burning Cookstove: An Experimental Study
This research parametrically investigates the effect of secondary air injection on the mass and size distribution of PM emitted during solid biomass combustion using a modular, experimental wood-burning cookstove platform.
A Low Cost, Re-usable, Electricity-Free Infant Warmer: Evaluation of Safety, Effectiveness, and Feasibility
The efficacy of a low-cost, re-usable, and non-electric infant warmer is evaluated in a hospital setting to prevent neonatal hypothermia. It is capable of maintaining 37 C for approximately six hours when a parent is not available for skin-to-skin care.
Reducing ultrafine particle emissions using air injection in wood-burning cookstoves
This paper investigates the effect of air injection on cooking performance, PM and gaseous emissions, and PM size distribution and number concentration. Although air injection can decrease total PM mass emitted, it is unclear if it reduces the number concentration of all PM emission sizes uniformly or concurrently increase the number of ultrafine particles per mass of fuel burned, which may be more harmful to human health.
A review of regulatory standard test methods for residential wood heaters and recommendations for their advancement
This study presents a comprehensive review of standardized wood heater test methods to identify fundamental experimental objectives and regulated performance metrics. Using the results of this review, recommendations are provided to make the test methods more accessible and representative of residential performance, while generating actionable data to motivate heater design improvements. This study elucidates the current state of standard test methods, and the developments needed to advance clean wood heater technologies and public policies.
Economic and greenhouse gas analysis of regional bioenergy-powered district energy systems in California
District energy systems (DES) have the potential to meet building power, heating and cooling needs efficiently and reliably, but further research is needed to understand their coupling with local renewable energy sources such as biomass. Here we assess the cost and greenhouse gas implications of using bioenergy from local organic waste to power DES in California communities.
Opportunities for installed combined heat and power (CHP) to increase grid flexibility in the U.S.
In this paper, we used CHP operating data and determined annual and monthly availability of the installed CHP capacity from various sectors (e.g., utility, independent power producer, commercial, and industrial) in all seven U.S. independent system operators and regional transmission organizations.
High thermoelectric figure of merit of porous Si nanowires from 300 to 700 K
We report the synthesis of large-area, wafer- scale arrays of porous silicon nanowires with ultra-thin Si crystallite size of ~4 nm. Concurrent measurements of thermal conductivity (κ), electrical conductivity (σ), and Seebeck coefficient (S) on the same nanowire show a ZT of 0.71 at 700 K, which is more than ~18 times higher than bulk Si. This ZT value is more than two times higher than any nanostructured Si-based thermoelectrics reported in the literature at 700 K.
Emissions from Heated Terpenoids Present in Vaporizable Cannabis Concentrates
To understand the emissions and impacts from vaporizable cannabis concentrates, we evaluated mixtures containing different proportions of 12 VCC terpenoids and high MW compounds. Terpenoids, thermal degradation byproducts, and ultrafine particles were quantified from all samples.
Investigation of biofuels from microorganism metabolism for use as anti-knock additives
This paper investigates the anti-knock properties of biofuels that can be produced from microorganism metabolic processes. The biofuels are rated using Research Octane Number (RON) and Blending Research Octane Number (BRON), which determine their potential as additives for fuel in spark ignition (SI) engines.
Research Octane Number of Primary and Mixed Alcohols from Biomass based Syngas
The performance of primary alcohols was experimentally determined using the research octane number (RON) and the blending research octane number (BRON). The primary alcohol mixture, or “AlcoMix,” consists of 75% ethanol, 11% 1-propanol, 8% 1-butanol, and 6% 1-pentanol and was approved by the U.S. EPA for use in blending with gasoline.
Predicting fuel performance for future HCCI engines
The purpose of this research is to investigate the impact of fuel composition on auto-ignition in homogeneous charge compression ignition (HCCI) engines in order to develop a future metric for predicting fuel performance in future HCCI engine technology.
Extending Lean Operating Limit and Reducing Emissions of Methane Spark-Ignited Engines Using a Microwave-Assisted Spark Plug
A microwave-assisted spark plug was used to extend the lean operating limit (lean limit) and reduce emissions of an engine burning methane-air. In-cylinder pressure data were collected at normalized air-fuel ratios of 1.46, 1.51, 1.57 1.68, and 1.75.
Extending the lean operation limits of a gasoline engine using a microwave-assisted sparkplug
We investigated the extension of the lean stability limits of gasoline-air mixtures using a microwave-assisted spark plug. Experiments are conducted on a 1200 RPM single-cylinder Waukesha Cooperative Fuel Research (CFR) engine at two compression ratios: 7:1 and 9:1; and four different levels of microwave energy input per cycle.
Increased Efficiency in SI Engine with Air Replaced by Oxygen in Argon Mixture
We investigate the role of both the compression ratio and the specific heat ratio on engine efficiency by conducting experiments comparing operation of a single-cylinder variable-compression-ratio engine with both hydrogen-air and hydrogen-oxygen-argon mixtures.
Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II
The purpose of this article is to assess VENT-II’s ability to predict combustion gas spillage events due to house depressurization by comparing VENT-II simulated results with experimental data for four appliance configurations.
Design, Construction and Testing of a Desktop Supersonic Wind Tunnel
A mobile and affordable, miniature wind tunnel to aid students in studying high-speed compressible flows was constructed and tested. Millimeter-sized nozzles of different contours were fabricated to produce supersonic flows at Mach 2.